Alpha-benzoin oxime in higher oxidation state 3d metal cluster chemistry: structural and magnetic study of a new Mn(III)(9) complex.

نویسندگان

  • Evangelia S Koumousi
  • Manolis J Manos
  • Christos Lampropoulos
  • Anastasios J Tasiopoulos
  • Wolfgang Wernsdorfer
  • George Christou
  • Theocharis C Stamatatos
چکیده

The initial employment of alpha-benzoin oxime (bzoxH(2)) in higher oxidation state 3d metal cluster chemistry has provided access to a new enneanuclear Mn(III) complex with an unprecedented metal-core topology consisting of two triangular [Mn(3)(mu(3)-Omicron(2-))(mu-OmicronNu)(3)](4+) fragments connected by a linear [Mn(3)(mu-OmicronNu)(6)](3+) unit. The Mn(III)(9) cluster is antiferromagnetically coupled and has an S = 3 spin ground state.

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عنوان ژورنال:
  • Inorganic chemistry

دوره 49 7  شماره 

صفحات  -

تاریخ انتشار 2010